The FTIR spectra of CH2F2 have been investigated in a region of atm. interest (1000-​1300 cm-​1) where four fundamentals ν3, ν5, ν7 and ν9 occur. These vibrations perturb each other by different Coriolis interactions and the forbidden ν5 borrows intensity from the neighboring levels. Furthermore, the v4=2 state has been found to interact with the v3=1 and v9=1 states by anharmonic and c-​type Coriolis resonances, resp. The spectral anal. resulted in the assignment of about 7500 rovibrational transitions which have been simultaneously fitted, together with microwave data available in literature (Hirota E. J Mol Spectrosc 1978; 69: 409-​420) [15] using the Watson's A-​redn. Hamiltonian in the Ir representation and the relevant perturbation operators. The model employed includes eight types of resonances within the pentad ν3/ν5/ν7/ν9/2ν4. A set of spectroscopic consts. for the four fundamentals as well as parameters for the v4=2 state and eighteen coupling terms have been detd. The simulations performed in different spectral regions well reproduce the exptl. data.

FTIR spectra of CH2F2 in the 1000-1300 cm-1 region: Rovibrational analysis and modeling of the Coriolis and anharmonic resonances in the ν3, ν5, ν7, ν9 and 2ν4 polyad

TAMASSIA, FILIPPO;CANE', ELISABETTA;VILLA, MATTIA
2016

Abstract

The FTIR spectra of CH2F2 have been investigated in a region of atm. interest (1000-​1300 cm-​1) where four fundamentals ν3, ν5, ν7 and ν9 occur. These vibrations perturb each other by different Coriolis interactions and the forbidden ν5 borrows intensity from the neighboring levels. Furthermore, the v4=2 state has been found to interact with the v3=1 and v9=1 states by anharmonic and c-​type Coriolis resonances, resp. The spectral anal. resulted in the assignment of about 7500 rovibrational transitions which have been simultaneously fitted, together with microwave data available in literature (Hirota E. J Mol Spectrosc 1978; 69: 409-​420) [15] using the Watson's A-​redn. Hamiltonian in the Ir representation and the relevant perturbation operators. The model employed includes eight types of resonances within the pentad ν3/ν5/ν7/ν9/2ν4. A set of spectroscopic consts. for the four fundamentals as well as parameters for the v4=2 state and eighteen coupling terms have been detd. The simulations performed in different spectral regions well reproduce the exptl. data.
Stoppa, Paolo; Tasinato, Nicola; Baldacci, Agostino; Pietropolli Charmet, Andrea; Giorgianni, Santi; Tamassia, Filippo; Cané, Elisabetta; Villa, Mattia
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/535794
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