The mononuclear complexes MoCl5L (L = 2,5-dihydrothiophene-1,1-dioxide), 1, and MoCl4L2 (L = dimethylsulfone, 2; diethylsulfone, 3; diphenylsulfone, 4) were obtained by the reactions of MoCl5 with the corresponding sulfones at room temperature in dichloromethane, and were characterized by analytical and magnetic data, and by X-ray crystallography in the cases of 1 and 2. The X-ray structure of 1 is the first one ever reported for an adduct of MoCl5 with a carbon-containing species.

Ferretti, E., Hayatifar, M., Marchetti, F., Pampaloni, G., Zacchini, S. (2015). Molybdenum(V) and molybdenum(IV) coordination compounds from the reactions of MoCl<inf>5</inf> with sulfones. POLYHEDRON, 100, 400-403 [10.1016/j.poly.2015.09.004].

Molybdenum(V) and molybdenum(IV) coordination compounds from the reactions of MoCl5 with sulfones

ZACCHINI, STEFANO
2015

Abstract

The mononuclear complexes MoCl5L (L = 2,5-dihydrothiophene-1,1-dioxide), 1, and MoCl4L2 (L = dimethylsulfone, 2; diethylsulfone, 3; diphenylsulfone, 4) were obtained by the reactions of MoCl5 with the corresponding sulfones at room temperature in dichloromethane, and were characterized by analytical and magnetic data, and by X-ray crystallography in the cases of 1 and 2. The X-ray structure of 1 is the first one ever reported for an adduct of MoCl5 with a carbon-containing species.
2015
Ferretti, E., Hayatifar, M., Marchetti, F., Pampaloni, G., Zacchini, S. (2015). Molybdenum(V) and molybdenum(IV) coordination compounds from the reactions of MoCl<inf>5</inf> with sulfones. POLYHEDRON, 100, 400-403 [10.1016/j.poly.2015.09.004].
Ferretti, Eleonora; Hayatifar, Mohammad; Marchetti, Fabio; Pampaloni, Guido; Zacchini, Stefano
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/535739
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