Photocatalysis enables the cascade reactions of indoles and CBr4 in MeOH through a C(sp2)H functionali- zation/methanolysis sequence. The title reaction provides an efficient access to indole 2- and 3-carboxylates in a single operation (no preinstallation of protecting as well as directing groups was required) with good yields under mild reaction conditions.
Yang, Q., Marchini, M., Xiao, W., Ceroni, P., Bandini, M. (2015). Visible-Light-Induced Direct Photocatalytic Carboxylation of Indoles with CBr4/MeOH. CHEMISTRY-A EUROPEAN JOURNAL, 21, 18052-18056 [10.1002/chem.201503787].
Visible-Light-Induced Direct Photocatalytic Carboxylation of Indoles with CBr4/MeOH
MARCHINI, MARIANNA;CERONI, PAOLA;BANDINI, MARCO
2015
Abstract
Photocatalysis enables the cascade reactions of indoles and CBr4 in MeOH through a C(sp2)H functionali- zation/methanolysis sequence. The title reaction provides an efficient access to indole 2- and 3-carboxylates in a single operation (no preinstallation of protecting as well as directing groups was required) with good yields under mild reaction conditions.File in questo prodotto:
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