Flameless oxy-combustion is a very efficient technology for treating low-ranking fuels with energy recovery,when operating in the high temperature range of 1200–1600 °C. However, the thermal valorization of these low-ranking fuels, containing a significant amount of vanadium, causes some problems due to the volatility and corrosiveness of V2O5 with ceramic and metal alloys at high temperatures. The formation of mixed V/Mg or V/Ni compounds,which are stable at high temperatures (1300 °C), was investigated in a tubular lab-scale furnace with a residence time of 2 s, starting fromsprayed aqueous VOSO4, MgSO4, andNiSO4 solutions. Itwas seen that MgSO4 and/or NiSO4 led first to the formation of MgO and NiO, which then reacted with V2O5 to produce fully inert Mg2V2O7,Mg3V2O8, andNi3V2O8. The experimental datawere combined with thermodynamic Equilibrium calculations, to predict the stability of the vanadates obtained. ©
N. Di Salvia, M.P. Malavasi, G. Di Salvia, A. Vaccari (2015). Formation of Ni and Mg vanadates during the flameless oxy-combustion of heavy fuels. FUEL PROCESSING TECHNOLOGY, 138, 534-539 [10.1016/j.fuproc.2015.06.033].
Formation of Ni and Mg vanadates during the flameless oxy-combustion of heavy fuels
VACCARI, ANGELO
2015
Abstract
Flameless oxy-combustion is a very efficient technology for treating low-ranking fuels with energy recovery,when operating in the high temperature range of 1200–1600 °C. However, the thermal valorization of these low-ranking fuels, containing a significant amount of vanadium, causes some problems due to the volatility and corrosiveness of V2O5 with ceramic and metal alloys at high temperatures. The formation of mixed V/Mg or V/Ni compounds,which are stable at high temperatures (1300 °C), was investigated in a tubular lab-scale furnace with a residence time of 2 s, starting fromsprayed aqueous VOSO4, MgSO4, andNiSO4 solutions. Itwas seen that MgSO4 and/or NiSO4 led first to the formation of MgO and NiO, which then reacted with V2O5 to produce fully inert Mg2V2O7,Mg3V2O8, andNi3V2O8. The experimental datawere combined with thermodynamic Equilibrium calculations, to predict the stability of the vanadates obtained. ©I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
