The first example of perfluoroalkyl methyl ester RfC(O)OMe (Rf = C3F7, C5F11) reduction by homogeneous catalytic hydrogenation with the ruthenium catalyst Ru-MACHOTM is herein reported. The hydrogenation process leads to the corresponding perfluorinated alcohols thus replacing sodium borohydride that has so far represented the state of art in perfluoro ester reduction.
Lazzari, D., Cassani, M.C., Bertola, M., Moreno, F.C., Torrente, D. (2013). Homogeneous catalytic hydrogenation of perfluoro methyl esters. RSC ADVANCES, 3(36), 15582-15584 [10.1039/c3ra43410a].
Homogeneous catalytic hydrogenation of perfluoro methyl esters
CASSANI, MARIA CRISTINA;
2013
Abstract
The first example of perfluoroalkyl methyl ester RfC(O)OMe (Rf = C3F7, C5F11) reduction by homogeneous catalytic hydrogenation with the ruthenium catalyst Ru-MACHOTM is herein reported. The hydrogenation process leads to the corresponding perfluorinated alcohols thus replacing sodium borohydride that has so far represented the state of art in perfluoro ester reduction.File in questo prodotto:
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