Solid [CuI(piperazine)0.5][infinity], characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed.

Maini, L., Braga, D., Mazzeo, P.P., Maschio, L., Rerat M., Manet, I., et al. (2015). Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state. DALTON TRANSACTIONS, 44, 13003-13006 [10.1039/C5DT02204E].

Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state

MAINI, LUCIA;BRAGA, DARIO;MAZZEO, PAOLO PIO;
2015

Abstract

Solid [CuI(piperazine)0.5][infinity], characterized by a structure with an infinite double chain of CuI, presents an unexpected dual luminescence. The short copper-copper distances allow the existence of both cluster-centered and 1-D delocalized electronic transitions, as emerged from theoretical calculations. Beyond the more common cluster-centered emission a higher energy band, which differs in lifetime and in temperature dependence, is observed.
2015
Maini, L., Braga, D., Mazzeo, P.P., Maschio, L., Rerat M., Manet, I., et al. (2015). Dual luminescence in solid CuI(piperazine): hypothesis of an emissive 1-D delocalized excited state. DALTON TRANSACTIONS, 44, 13003-13006 [10.1039/C5DT02204E].
Maini, L.; Braga, D.; Mazzeo, P. P.; Maschio, L.; Rerat M.; Manet, I.; Ventura, B.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/519342
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