The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (DE01 = 22.364(1) MHz) by measuring the very weak lc-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all 13C monosubstituted isotopologues have been assigned and measured in natural abundance, leading to an accurate structure of the heavy atoms frame.
Favero, L.B., Li, W., Spadini, G., Caminati, W. (2015). Ring puckering splitting and structure of indan. JOURNAL OF MOLECULAR SPECTROSCOPY, 316, 45-48 [10.1016/j.jms.2015.08.001].
Ring puckering splitting and structure of indan
LI, WEIXING;SPADINI, GIANCARLO;CAMINATI, WALTHER
2015
Abstract
The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (DE01 = 22.364(1) MHz) by measuring the very weak lc-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all 13C monosubstituted isotopologues have been assigned and measured in natural abundance, leading to an accurate structure of the heavy atoms frame.File in questo prodotto:
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