The rotational spectrum of the 1:1 complex between formic acid and formaldehyde shows that the two units are linked together through a "classical" (OH···O) and a weak (CH···O) hydrogen bond. The molecular system appears quite rigid, and no effects of the internal motions have been observed in the spectrum.

Gou, Q., Favero, L., Bahamyirou, S., Xia, Z., Caminati, W. (2014). Interactions between carboxylic acids and aldehydes: A rotational study of HCOOH-CH2O. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 118(45), 10738-10741 [10.1021/jp506600p].

Interactions between carboxylic acids and aldehydes: A rotational study of HCOOH-CH2O

GOU, QIAN;BAHAMYIROU, SOMANA SYLVANA;CAMINATI, WALTHER
2014

Abstract

The rotational spectrum of the 1:1 complex between formic acid and formaldehyde shows that the two units are linked together through a "classical" (OH···O) and a weak (CH···O) hydrogen bond. The molecular system appears quite rigid, and no effects of the internal motions have been observed in the spectrum.
2014
Gou, Q., Favero, L., Bahamyirou, S., Xia, Z., Caminati, W. (2014). Interactions between carboxylic acids and aldehydes: A rotational study of HCOOH-CH2O. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 118(45), 10738-10741 [10.1021/jp506600p].
Gou, Q.; Favero, L.B.; Bahamyirou, S.S.; Xia, Z.; Caminati, W.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/518766
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