The rotational spectrum of the adduct pyridine-methane shows that methane links to an aromatic molecule apparently through a C-H···π weak hydrogen bond. The shape and the internal dynamics behaviour of this complex are very similar to that of the van der Waals complexes involving aromatic molecules with rare gases.
Interactions between alkanes and aromatic molecules: A rotational study of pyridine-methane / Gou, Q.; Spada, L.; Vallejo-Lopez, M.; Lesarri, A.; Cocinero, E.J.; Caminati, W.. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 16:26(2014), pp. 13041-13046. [10.1039/c4cp00204k]
Interactions between alkanes and aromatic molecules: A rotational study of pyridine-methane
GOU, QIAN;SPADA, LORENZO;CAMINATI, WALTHER
2014
Abstract
The rotational spectrum of the adduct pyridine-methane shows that methane links to an aromatic molecule apparently through a C-H···π weak hydrogen bond. The shape and the internal dynamics behaviour of this complex are very similar to that of the van der Waals complexes involving aromatic molecules with rare gases.File in questo prodotto:
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