The pulsed jet Fourier transform microwave spectrum of the 1:1 complex between CF3Cl and CH3F shows that the two moieties are linked by a Cl···F halogen bond (RCl···F = 2.995 Å). The two symmetric tops CF3 and CH3 undergo free or almost free internal rotations, which alter the "rigid" value of the rotational constant A by almost 1 order of magnitude.
Gou, Q., Spada, L., Cocinero, E., Caminati, W. (2014). Halogen-Halogen links and internal dynamics in adducts of freons. THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 5(9), 1591-1595 [10.1021/jz500600w].
Halogen-Halogen links and internal dynamics in adducts of freons
GOU, QIAN;SPADA, LORENZO;CAMINATI, WALTHER
2014
Abstract
The pulsed jet Fourier transform microwave spectrum of the 1:1 complex between CF3Cl and CH3F shows that the two moieties are linked by a Cl···F halogen bond (RCl···F = 2.995 Å). The two symmetric tops CF3 and CH3 undergo free or almost free internal rotations, which alter the "rigid" value of the rotational constant A by almost 1 order of magnitude.File in questo prodotto:
Eventuali allegati, non sono esposti
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
