Novel iron complexes bearing both cyclopentadienone and N-heterocyclic carbene ancillary ligands were obtained by a straightforward synthesis from Fe2(CO)9. The preparation represents a rare example of silver transmetallation involving iron. The reaction is general and occurs in the presence of variously functionalized NHC and cyclopentadienones.
Cingolani, A., Cesari, C., Zacchini, S., Zanotti, V., Cassani, M.C., Mazzoni, R. (2015). Straightforward synthesis of iron cyclopentadienone N-heterocyclic carbene complexes. DALTON TRANSACTIONS, 44, 19063-19067 [10.1039/c5dt03071d].
Straightforward synthesis of iron cyclopentadienone N-heterocyclic carbene complexes
CINGOLANI, ANDREA;CESARI, CRISTIANA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;CASSANI, MARIA CRISTINA;MAZZONI, RITA
2015
Abstract
Novel iron complexes bearing both cyclopentadienone and N-heterocyclic carbene ancillary ligands were obtained by a straightforward synthesis from Fe2(CO)9. The preparation represents a rare example of silver transmetallation involving iron. The reaction is general and occurs in the presence of variously functionalized NHC and cyclopentadienones.File in questo prodotto:
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