Novel iron complexes bearing both cyclopentadienone and N-heterocyclic carbene ancillary ligands were obtained by a straightforward synthesis from Fe2(CO)9. The preparation represents a rare example of silver transmetallation involving iron. The reaction is general and occurs in the presence of variously functionalized NHC and cyclopentadienones.
Straightforward synthesis of iron cyclopentadienone N-heterocyclic carbene complexes
CINGOLANI, ANDREA;CESARI, CRISTIANA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;CASSANI, MARIA CRISTINA;MAZZONI, RITA
2015
Abstract
Novel iron complexes bearing both cyclopentadienone and N-heterocyclic carbene ancillary ligands were obtained by a straightforward synthesis from Fe2(CO)9. The preparation represents a rare example of silver transmetallation involving iron. The reaction is general and occurs in the presence of variously functionalized NHC and cyclopentadienones.File in questo prodotto:
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