A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.
Bartoli, G., Bosco, M., Carlone, A., Locatelli, M., Marcantoni, E., Melchiorre, P., et al. (2006). A new, mild, general and efficient route to aryl ethyl carbonates in solvent-free conditions promoted by magnesium perchlorate. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006(19), 4429-4434 [10.1002/ejoc.200600366].
A new, mild, general and efficient route to aryl ethyl carbonates in solvent-free conditions promoted by magnesium perchlorate
BARTOLI, GIUSEPPE;BOSCO, MARCELLA;CARLONE, ARMANDO;LOCATELLI, MANUELA;MELCHIORRE, PAOLO;PALAZZI, PAOLO;SAMBRI, LETIZIA
2006
Abstract
A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.File in questo prodotto:
Eventuali allegati, non sono esposti
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
