A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.
A new, mild, general and efficient route to aryl ethyl carbonates in solvent-free conditions promoted by magnesium perchlorate / Bartoli, G.; Bosco, M.; Carlone, A.; Locatelli, M.; Marcantoni, E.; Melchiorre, P.; Palazzi, P.; Sambri, L.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1099-0690. - STAMPA. - 2006:19(2006), pp. 4429-4434. [10.1002/ejoc.200600366]
A new, mild, general and efficient route to aryl ethyl carbonates in solvent-free conditions promoted by magnesium perchlorate
BARTOLI, GIUSEPPE;BOSCO, MARCELLA;CARLONE, ARMANDO;LOCATELLI, MANUELA;MELCHIORRE, PAOLO;PALAZZI, PAOLO;SAMBRI, LETIZIA
2006
Abstract
A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
