The role of tectonic shear strain on the illitization mechanism of mixed-layers illite–smectite. A case study from a fault zone in the Northern Apennines, Italy

The influence of tectonic strain on the diagenetic degree and illitization process of mixed-layers illite–smectite at shallow crustal conditions was studied. For this purpose, the modal composition of clay fraction and illite FWHM parameters of argillites deformed by a regionalscale fault zone were studied in detail by XRD, chemical analyses and by SEM observations. Analyses were performed on deformed samples of the fault rock and compared with the non-deformed rocks off the fault zone. In addition, this paper reports a detailed comparative analysis of deformed (shear surfaces and cleavage domains) and non-deformed domains (lithon cores) of a scaly fabric in the fault rock. A systematic increase in illite concentration, a decrease of Ku¨bler index and FWHM(002) values, and an enrichment of K+ ions were observed in cleavage domains with respect to the non-deformed sediments off the fault zone and the lithon cores within the fault rock. Migration of K+-rich fluids along scaly cleavage domains causes progressive conversion of smectite-rich I–S to illite-rich I–S and thickening of illite crystallites along the c-direction. Changes in mineralogical and crystallographic parameters, therefore, seem to be strongly controlled by shear plane development in highly sheared rocks.