The trimer of difluoromethane, (CH2F2)3, has been characterized by supersonic jet Fourier transform microwave spectroscopy. The rotational spectrum displays all types (a, b and c) of transitions, showing that the adduct does not possess any element of molecular symmetry. The investigation of the three 13C species in natural abundance indicates that the three carbon atoms form a triangle where the C-C distances are 3.648(2), 3.825(8) and 3.942(6) Å, respectively. The three subunits are held together by nine CHF weak hydrogen bonds.
S. Blanco, S. Melandri, P. Ottaviani, W. Caminati (2007). Shapes and Noncovalent Interactions of Oligomers: The Rotational Spectrum of the Difluoromethane Trimer. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129, 2700-2703 [10.1021/ja068599b].
Shapes and Noncovalent Interactions of Oligomers: The Rotational Spectrum of the Difluoromethane Trimer
MELANDRI, SONIA;OTTAVIANI, PAOLO;CAMINATI, WALTHER
2007
Abstract
The trimer of difluoromethane, (CH2F2)3, has been characterized by supersonic jet Fourier transform microwave spectroscopy. The rotational spectrum displays all types (a, b and c) of transitions, showing that the adduct does not possess any element of molecular symmetry. The investigation of the three 13C species in natural abundance indicates that the three carbon atoms form a triangle where the C-C distances are 3.648(2), 3.825(8) and 3.942(6) Å, respectively. The three subunits are held together by nine CHF weak hydrogen bonds.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
