A novel series of functionalized polythiophenes incorporating 3-(w-bromoalkyl) pendants are synthesized by electrochemical polymerization. The effect of the solvent on the electrosynthesis is investigated. The polymeric films are characterized using cyclic voltammetry, FT-IR, AFM and SEM microscopy. The poly[3-(6-bromohexyl)thiophene] film cast on GC or ITO electrode surface is compared with a sample obtained by a chemical method.
B. Ballarin, M. Lanzi, L. Paganin, G. Cesari (2007). Electrochemical synthesis and characterization of poly[3-(w-bromoalkyl)thiophene]s. ELECTROCHIMICA ACTA, 52, 4087-4091 [10.1016/j.electacta.2006.11.026].
Electrochemical synthesis and characterization of poly[3-(w-bromoalkyl)thiophene]s
BALLARIN, BARBARA;LANZI, MASSIMILIANO;PAGANIN, LUISA;CESARI, GAIA
2007
Abstract
A novel series of functionalized polythiophenes incorporating 3-(w-bromoalkyl) pendants are synthesized by electrochemical polymerization. The effect of the solvent on the electrosynthesis is investigated. The polymeric films are characterized using cyclic voltammetry, FT-IR, AFM and SEM microscopy. The poly[3-(6-bromohexyl)thiophene] film cast on GC or ITO electrode surface is compared with a sample obtained by a chemical method.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
