Polymer-supported alkoxycarbonylcyclopentadienyl rhodium(I) complexes have been obtained through immobilization of [RhC5H4CO2(CH2)2O2C-Im(NBD)] (2) (Im = imidazole) on an (aminomethyl)polystyrene resin. An alternative approach toward the supportation of [RhC5H4CO2(CH2)2OH(NBD)] (1) on a Wang resin has been also developed. Spectroscopic characterization of all the new functionalised resins with particular accent on ICP-OES measurements is presented and discussed.
L. Busetto, P.L. Buldini, M.C. Cassani, R. Mazzoni (2006). Clean and Efficient Synthesis of Air Stable Polymer-Supported Alkoxycarbonylcyclopentadienyl Rhodium(I) Complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691, 573-578 [10.1016/j.jorganchem.2005.09.028].
Clean and Efficient Synthesis of Air Stable Polymer-Supported Alkoxycarbonylcyclopentadienyl Rhodium(I) Complexes
BUSETTO, LUIGI;CASSANI, MARIA CRISTINA;MAZZONI, RITA
2006
Abstract
Polymer-supported alkoxycarbonylcyclopentadienyl rhodium(I) complexes have been obtained through immobilization of [RhC5H4CO2(CH2)2O2C-Im(NBD)] (2) (Im = imidazole) on an (aminomethyl)polystyrene resin. An alternative approach toward the supportation of [RhC5H4CO2(CH2)2OH(NBD)] (1) on a Wang resin has been also developed. Spectroscopic characterization of all the new functionalised resins with particular accent on ICP-OES measurements is presented and discussed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
