The new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes [Rh{5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and [Rh{5-C5H4CO2(CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures.
L. Busetto, M.C. Cassani, R. Mazzoni, V.G. Albano, P. Sabatino (2005). One-Pot Synthesis of the New Dianionic Ligand [Na]2[C5H4CO2(CH2)2NTs]; Preparation and Structures of Two Rhodium Derivatives. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 818-824 [10.1016/j.jorganchem.2004.10.024].
One-Pot Synthesis of the New Dianionic Ligand [Na]2[C5H4CO2(CH2)2NTs]; Preparation and Structures of Two Rhodium Derivatives
BUSETTO, LUIGI;CASSANI, MARIA CRISTINA;MAZZONI, RITA;ALBANO, VINCENZO GIULIO;SABATINO, PIERA
2005
Abstract
The new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes [Rh{5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and [Rh{5-C5H4CO2(CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
