The new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes [Rh{5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and [Rh{5-C5H4CO2(CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures.
Titolo: | One-Pot Synthesis of the New Dianionic Ligand [Na]2[C5H4CO2(CH2)2NTs]; Preparation and Structures of Two Rhodium Derivatives |
Autore/i: | BUSETTO, LUIGI; CASSANI, MARIA CRISTINA; MAZZONI, RITA; ALBANO, VINCENZO GIULIO; SABATINO, PIERA |
Autore/i Unibo: | |
Anno: | 2005 |
Rivista: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.jorganchem.2004.10.024 |
Abstract: | The new dianionic ligand [Na]2[C5H4CO2(CH2)2NTs] (1) having an alkoxycarbonyl and an amide group in the same side chain has been prepared by a single step, high yield procedure. The synthesis of the related rhodium complexes [Rh{5-C5H4CO2(CH2)2N(H)Ts}(NBD)] (3) and [Rh{5-C5H4CO2(CH2)2N(Me)Ts}(NBD)] (4) is reported as well as their X-ray molecular structures. |
Data prodotto definitivo in UGOV: | 2005-10-06 10:54:59 |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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