Extreme frequency accuracy and high sensitivity are obtained with a novel comb-locked cavity-ring-down spectrometer operating in the near-infrared from 1.5 to 1.63 μm. A key feature of our approach is the tight frequency locking of the probe laser to the comb, ensuring very high reproducibility and accuracy to the frequency axis upon scanning the comb repetition rate, as well as an efcient light injection into a length-swept high-fnesse passive cavity containing the gas sample. Spectroscopic tests on the (30012) ← (00001) P14e line of CO 2 at ∼1.57 μm demonstrate an accuracy of ∼17 kHz on the line center frequency in a Doppler broadening regime over the time scale of about 5 min, corresponding to four consecutive spectral scans of the absorption line. Over a single scan, which consists of 1500 spectral points over 75 s, the limit of detection is as low as 5.7 × 10^−11 cm^−1 .
Davide Gatti, Tommaso Sala, Riccardo Gotti, Lorenzo Cocola, Luca Poletto, Marco Prevedelli, et al. (2015). Comb-locked cavity ring-down spectrometer. THE JOURNAL OF CHEMICAL PHYSICS, 142, 074201-1-074201-8 [10.1063/1.4907939].
Comb-locked cavity ring-down spectrometer
PREVEDELLI, MARCO;
2015
Abstract
Extreme frequency accuracy and high sensitivity are obtained with a novel comb-locked cavity-ring-down spectrometer operating in the near-infrared from 1.5 to 1.63 μm. A key feature of our approach is the tight frequency locking of the probe laser to the comb, ensuring very high reproducibility and accuracy to the frequency axis upon scanning the comb repetition rate, as well as an efcient light injection into a length-swept high-fnesse passive cavity containing the gas sample. Spectroscopic tests on the (30012) ← (00001) P14e line of CO 2 at ∼1.57 μm demonstrate an accuracy of ∼17 kHz on the line center frequency in a Doppler broadening regime over the time scale of about 5 min, corresponding to four consecutive spectral scans of the absorption line. Over a single scan, which consists of 1500 spectral points over 75 s, the limit of detection is as low as 5.7 × 10^−11 cm^−1 .I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
