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EnglishElectron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations.
| Titolo: | Electron attachment to strongly polar clusters: formamide molecule and clusters. |
| Autore/i: | M. Seydou; MODELLI, ALBERTO; B. Lucas; K. Konate; C. Desfrançois; J. P. Schermann |
| Autore/i Unibo: | |
| Anno: | 2005 |
| Rivista: | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1140/epjd/e2005-00089-5 |
| Abstract: | Electron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations. |
| Data prodotto definitivo in UGOV: | 2005-09-19 10:51:22 |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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http://hdl.handle.net/11585/4205
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