Electron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations.

Electron attachment to strongly polar clusters: formamide molecule and clusters.

MODELLI, ALBERTO;
2005

Abstract

Electron localization is studied in formamide cluster anions. The isolated formamide molecule has a large dipole moment and its clusters can give birth to multipole-bound anions as well as valence anions. The vertical electron affinity of tyhe isolated molecule is determined by means of Electron Transmission Spectroscopy. The anion formation process is studied as a function of cluster size with Rydberg Electron Transfer Spectroscopy. The localization properties of the cluster anions are investiagted with Density Functional Theory calculations.
M. Seydou ; A. Modelli; B. Lucas; K.Konate; C. Desfrançois; J.P. Schermann
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/4205
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