Cationic Pd(II) complexes modified with achiral C2v-symmetric α-diimine ligands allow preparation of atactic or isotactic stereoblock CO/p-methylstyrene copolymers; both catalyst activity and polyketone microstructure depend on the choice of α-diimine substituents and counterion.
BINOTTI B., CARFAGNA C, ZUCCACCIA C., MACCHIONI A. (2005). From Atactic to Isotactic CO/p-Methylstyrene Copolymer by Proper Modifications of Pd(II) Catalysts Bearing Achiral alpha-Diimines. CHEMICAL COMMUNICATIONS, 1, 92-94 [10.1039/B411214H].
From Atactic to Isotactic CO/p-Methylstyrene Copolymer by Proper Modifications of Pd(II) Catalysts Bearing Achiral alpha-Diimines
CARFAGNA, CARLA;
2005
Abstract
Cationic Pd(II) complexes modified with achiral C2v-symmetric α-diimine ligands allow preparation of atactic or isotactic stereoblock CO/p-methylstyrene copolymers; both catalyst activity and polyketone microstructure depend on the choice of α-diimine substituents and counterion.File in questo prodotto:
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