The bis (homoleptic) palladium (II) complexes of the extended aromatic ligands eilatin ([Pd(eil) 2][BF4] 2) and dipyridophenazine ([Pd (dppz) 2][BF4] 2,[Pd (dppz) 2][PF6] 2) were synthesized and employed in the copolymerization of carbon monoxide and styrene, their activity found to exceed that of the parent complex [Pd (phen) 2][BF4] 2.
S. D. BERGMAN, I. GOLDBERG, CARFAGNA C, L. MOSCA, M. KOL, B. MILANI (2006). Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Copolymerization. ORGANOMETALLICS, 25(26), 6014-6018 [10.1021/om060624z].
Palladium Complexes Containing Large Fused Aromatic N-N Ligands as Efficient Catalysts for the CO/Styrene Copolymerization
CARFAGNA, CARLA;
2006
Abstract
The bis (homoleptic) palladium (II) complexes of the extended aromatic ligands eilatin ([Pd(eil) 2][BF4] 2) and dipyridophenazine ([Pd (dppz) 2][BF4] 2,[Pd (dppz) 2][PF6] 2) were synthesized and employed in the copolymerization of carbon monoxide and styrene, their activity found to exceed that of the parent complex [Pd (phen) 2][BF4] 2.File in questo prodotto:
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