The weak electrostatic interaction between nitro and carbonyl moieties has been observed by means of variabletemperature NMR spectroscopy. Its energetic contribution was evaluated to be about 3 kcalmol-1 by DFT calculations, and confirmed by the measurement of internal energy barriers to the rotation of suitable nitroaryl rings

Michel Chiarucci, Alessia Ciogli, Michele Mancinelli, Silvia Ranieri, Andrea Mazzanti (2014). The Experimental Observation of the Intramolecular NO2/CO Interaction in Solution. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 53(21), 5509-5513 [10.1002/ange.201402366].

The Experimental Observation of the Intramolecular NO2/CO Interaction in Solution

CHIARUCCI, MICHEL;MANCINELLI, MICHELE;RANIERI, SILVIA;MAZZANTI, ANDREA
2014

Abstract

The weak electrostatic interaction between nitro and carbonyl moieties has been observed by means of variabletemperature NMR spectroscopy. Its energetic contribution was evaluated to be about 3 kcalmol-1 by DFT calculations, and confirmed by the measurement of internal energy barriers to the rotation of suitable nitroaryl rings
2014
Michel Chiarucci, Alessia Ciogli, Michele Mancinelli, Silvia Ranieri, Andrea Mazzanti (2014). The Experimental Observation of the Intramolecular NO2/CO Interaction in Solution. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 53(21), 5509-5513 [10.1002/ange.201402366].
Michel Chiarucci;Alessia Ciogli;Michele Mancinelli;Silvia Ranieri;Andrea Mazzanti
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/373116
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 10
  • ???jsp.display-item.citation.isi??? 10
social impact