Commercially available homogeneous ruthenium catalysts are useful tools for the transformation of enviromentally compatible perfluorinated building blocks. This paper presents examples of reactions that make use of three different ruthenium complexes: the ruthenium(II) tri-chelated complex carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II) (a commercial catalyst known as Ru-MACHO), [RuClH(CO)(PPh3)3] and 2nd generation Grubbs’ catalyst CatMETium_RF3
Dario Lazzari, Maria Cristina Cassani, Maurizio Bertola, Roberto Rossato (2014). HOMOGENEOUS RUTHENIUM CATALYSTS FOR THE TRANSFORMATION OF PERFLUORINATED BUILDING BLOCKS. LA CHIMICA E L'INDUSTRIA, 4, 45-50.
HOMOGENEOUS RUTHENIUM CATALYSTS FOR THE TRANSFORMATION OF PERFLUORINATED BUILDING BLOCKS
CASSANI, MARIA CRISTINA;
2014
Abstract
Commercially available homogeneous ruthenium catalysts are useful tools for the transformation of enviromentally compatible perfluorinated building blocks. This paper presents examples of reactions that make use of three different ruthenium complexes: the ruthenium(II) tri-chelated complex carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II) (a commercial catalyst known as Ru-MACHO), [RuClH(CO)(PPh3)3] and 2nd generation Grubbs’ catalyst CatMETium_RF3I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
