Commercially available homogeneous ruthenium catalysts are useful tools for the transformation of enviromentally compatible perfluorinated building blocks. This paper presents examples of reactions that make use of three different ruthenium complexes: the ruthenium(II) tri-chelated complex carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II) (a commercial catalyst known as Ru-MACHO), [RuClH(CO)(PPh3)3] and 2nd generation Grubbs’ catalyst CatMETium_RF3
HOMOGENEOUS RUTHENIUM CATALYSTS FOR THE TRANSFORMATION OF PERFLUORINATED BUILDING BLOCKS
CASSANI, MARIA CRISTINA;
2014
Abstract
Commercially available homogeneous ruthenium catalysts are useful tools for the transformation of enviromentally compatible perfluorinated building blocks. This paper presents examples of reactions that make use of three different ruthenium complexes: the ruthenium(II) tri-chelated complex carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II) (a commercial catalyst known as Ru-MACHO), [RuClH(CO)(PPh3)3] and 2nd generation Grubbs’ catalyst CatMETium_RF3File in questo prodotto:
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