A straightforward and efficient synthetic route to novel Ru N-heterocyclic carbene (NHC) complexes by transmetallation of non-bulky silver NHC to ruthenium dicarbonyl tetraarylcyclopentadienone is described. The same procedure with sterically demanding NHC leads to unprecedented heterobimetallic Ru–Ag(NHC) complexes.
Sterically driven synthesis of ruthenium and ruthenium–silver N-heterocyclic carbene complexes / C. Cesari; S. Conti; S. Zacchini; V. Zanotti; M. C. Cassani; R. Mazzoni. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - ELETTRONICO. - 43:(2014), pp. 17240-17243. [10.1039/C4DT02747G]
Sterically driven synthesis of ruthenium and ruthenium–silver N-heterocyclic carbene complexes
CESARI, CRISTIANA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;CASSANI, MARIA CRISTINA;MAZZONI, RITA
2014
Abstract
A straightforward and efficient synthetic route to novel Ru N-heterocyclic carbene (NHC) complexes by transmetallation of non-bulky silver NHC to ruthenium dicarbonyl tetraarylcyclopentadienone is described. The same procedure with sterically demanding NHC leads to unprecedented heterobimetallic Ru–Ag(NHC) complexes.File in questo prodotto:
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