A straightforward and efficient synthetic route to novel Ru N-heterocyclic carbene (NHC) complexes by transmetallation of non-bulky silver NHC to ruthenium dicarbonyl tetraarylcyclopentadienone is described. The same procedure with sterically demanding NHC leads to unprecedented heterobimetallic Ru–Ag(NHC) complexes.
C. Cesari, S. Conti, S. Zacchini, V. Zanotti, M. C. Cassani, R. Mazzoni (2014). Sterically driven synthesis of ruthenium and ruthenium–silver N-heterocyclic carbene complexes. DALTON TRANSACTIONS, 43, 17240-17243 [10.1039/C4DT02747G].
Sterically driven synthesis of ruthenium and ruthenium–silver N-heterocyclic carbene complexes
CESARI, CRISTIANA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;CASSANI, MARIA CRISTINA;MAZZONI, RITA
2014
Abstract
A straightforward and efficient synthetic route to novel Ru N-heterocyclic carbene (NHC) complexes by transmetallation of non-bulky silver NHC to ruthenium dicarbonyl tetraarylcyclopentadienone is described. The same procedure with sterically demanding NHC leads to unprecedented heterobimetallic Ru–Ag(NHC) complexes.File in questo prodotto:
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