The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been studied in an ion trap mass spectrometer. The reactions of halogen substituted thiophenes lead to the formation of a new C–C bond between the cyclopentadiene ring and the thiophene with the loss of a neutral HX. The reaction mechanism has been investigated by means of DFT calculations.
Reactions of C5H5M+ (M=Fe, Ni) with substituted thiophenes / G. Innorta; S. Torroni. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 691(23):(2006), pp. 4931-4936. [10.1016/j.jorganchem.2006.08.035]
Reactions of C5H5M+ (M=Fe, Ni) with substituted thiophenes.
INNORTA, GIUSEPPE;TORRONI, SANDRO
2006
Abstract
The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been studied in an ion trap mass spectrometer. The reactions of halogen substituted thiophenes lead to the formation of a new C–C bond between the cyclopentadiene ring and the thiophene with the loss of a neutral HX. The reaction mechanism has been investigated by means of DFT calculations.File in questo prodotto:
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