The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been studied in an ion trap mass spectrometer. The reactions of halogen substituted thiophenes lead to the formation of a new C–C bond between the cyclopentadiene ring and the thiophene with the loss of a neutral HX. The reaction mechanism has been investigated by means of DFT calculations.
G. Innorta, S. Torroni (2006). Reactions of C5H5M+ (M=Fe, Ni) with substituted thiophenes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 691(23), 4931-4936 [10.1016/j.jorganchem.2006.08.035].
Reactions of C5H5M+ (M=Fe, Ni) with substituted thiophenes.
INNORTA, GIUSEPPE;TORRONI, SANDRO
2006
Abstract
The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been studied in an ion trap mass spectrometer. The reactions of halogen substituted thiophenes lead to the formation of a new C–C bond between the cyclopentadiene ring and the thiophene with the loss of a neutral HX. The reaction mechanism has been investigated by means of DFT calculations.File in questo prodotto:
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