The arylidene malonates with two different geminal carboxylate functions, a suitable class of substrates of several synthetic and pharmacological studies, are easily available through Knoevenagel condensation of ethyl tert-butyl malonate and different aromatic aldehydes. The results have increased the potentialities of CeCl3Æ7H2O–NaI system as a type of water-tolerant green Lewis acid promoter for carbon–carbon bond forming procedures.

The CeCl3.7H2O-NaI system as promoter in the synthesis of functionalized trisubstituted alkenes via Knoevenagel condensation / G. Bartoli; R. Beleggia; S. Giuli; A. Giuliani; E. Marcantoni; M. Massaccesi; M. Paoletti. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 47:(2006), pp. 6501-6504. [10.1016/j.tetlet.2006.07.031]

The CeCl3.7H2O-NaI system as promoter in the synthesis of functionalized trisubstituted alkenes via Knoevenagel condensation.

BARTOLI, GIUSEPPE;
2006

Abstract

The arylidene malonates with two different geminal carboxylate functions, a suitable class of substrates of several synthetic and pharmacological studies, are easily available through Knoevenagel condensation of ethyl tert-butyl malonate and different aromatic aldehydes. The results have increased the potentialities of CeCl3Æ7H2O–NaI system as a type of water-tolerant green Lewis acid promoter for carbon–carbon bond forming procedures.
2006
The CeCl3.7H2O-NaI system as promoter in the synthesis of functionalized trisubstituted alkenes via Knoevenagel condensation / G. Bartoli; R. Beleggia; S. Giuli; A. Giuliani; E. Marcantoni; M. Massaccesi; M. Paoletti. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 47:(2006), pp. 6501-6504. [10.1016/j.tetlet.2006.07.031]
G. Bartoli; R. Beleggia; S. Giuli; A. Giuliani; E. Marcantoni; M. Massaccesi; M. Paoletti
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/34891
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