A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.

G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, E. Marcantoni, P. Melchiorre, et al. (2006). A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, /, 4429-4434.

A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate

BARTOLI, GIUSEPPE;BOSCO, MARCELLA;CARLONE, ARMANDO;LOCATELLI, MANUELA;MELCHIORRE, PAOLO;PALAZZI, PAOLO;SAMBRI, LETIZIA
2006

Abstract

A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.
2006
G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, E. Marcantoni, P. Melchiorre, et al. (2006). A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, /, 4429-4434.
G. Bartoli; M. Bosco; A. Carlone; M. Locatelli; E. Marcantoni; P. Melchiorre; P. Palazzi; L. Sambri
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/34867
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