A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability.
Titolo: | A new Mild, General and Efficient Route to Aromatic Ethyl Carbonates in Solvent Free Conditions Promoted by Magnesium Perchlorate |
Autore/i: | BARTOLI, GIUSEPPE; BOSCO, MARCELLA; CARLONE, ARMANDO; LOCATELLI, MANUELA; E. Marcantoni; MELCHIORRE, PAOLO; PALAZZI, PAOLO; SAMBRI, LETIZIA |
Autore/i Unibo: | |
Anno: | 2006 |
Rivista: | |
Abstract: | A new, general and mild method for the direct synthesis of aryl and alkyl ethyl carbonates promoted by a Lewis acid is reported. The reaction proceeds smoothly with diethyl dicarbonate in the presence of Mg(ClO4)2, a specific activator of 1,3-dicarbonyl compounds, and shows general applicability. |
Data prodotto definitivo in UGOV: | 2007-02-19 12:08:07 |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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