A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru3(CO)12 with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.
Cristiana Cesari, Letizia Sambri, Stefano Zacchini, Valerio Zanotti, Rita Mazzoni (2014). Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes. ORGANOMETALLICS, 33, 2814-2819 [10.1021/om500335m].
Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes
CESARI, CRISTIANA;SAMBRI, LETIZIA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;MAZZONI, RITA
2014
Abstract
A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru3(CO)12 with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
