A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru3(CO)12 with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.
Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes / Cristiana Cesari;Letizia Sambri;Stefano Zacchini;Valerio Zanotti;Rita Mazzoni. - In: ORGANOMETALLICS. - ISSN 0276-7333. - ELETTRONICO. - 33:(2014), pp. 2814-2819. [10.1021/om500335m]
Microwave-Assisted Synthesis of Functionalized Shvo-Type Complexes
CESARI, CRISTIANA;SAMBRI, LETIZIA;ZACCHINI, STEFANO;ZANOTTI, VALERIO;MAZZONI, RITA
2014
Abstract
A simple and expeditious microwave-assisted procedure for the synthesis of a variety of Shvo-type ruthenium complexes has been developed by reacting Ru3(CO)12 with variously functionalized tetraarylcyclopentadienones under microwave irradiation in MeOH. Ligand precursors have also been prepared under microwave heating by a bis-aldol condensation of 1,3-diphenylacetone with variously functionalized aromatic diketones. All the reactions were very fast and clean, leading to good yields and purities.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
