The rotational spectra of the main isotopomer, of the 29Si and of all 13C isotopologues of axial and equatorial forms of 1-fluoro-silacyclohexane have been measured by conventional (only main species) and molecular beam Fourier transform microwave spectroscopy. r0 and partial rs structures are given separately for the two forms. The main structural differences are discussed. From dipole moments and relative intensity measurements, a slight preference (EEq – EAx = 42 ± 24 cm-1) for the axial conformer was found. The rotational spectra of some, the most intense, vibrational satellites have also been measured. They belong to the ring-puckering motions.
L.B.Favero, B.Velino, W.Caminati, I.Arnason, A.Kvaran (2006). Relative energy and structural differences of axial and equatorial 1-fluoro-1-silacyclohexane. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 110, 9995-9999 [10.1021/jp061583n].
Relative energy and structural differences of axial and equatorial 1-fluoro-1-silacyclohexane
VELINO, BIAGIO;CAMINATI, WALTHER;
2006
Abstract
The rotational spectra of the main isotopomer, of the 29Si and of all 13C isotopologues of axial and equatorial forms of 1-fluoro-silacyclohexane have been measured by conventional (only main species) and molecular beam Fourier transform microwave spectroscopy. r0 and partial rs structures are given separately for the two forms. The main structural differences are discussed. From dipole moments and relative intensity measurements, a slight preference (EEq – EAx = 42 ± 24 cm-1) for the axial conformer was found. The rotational spectra of some, the most intense, vibrational satellites have also been measured. They belong to the ring-puckering motions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
