The 1 : 2 molar reactions of MoCl5, in dichloromethane at room temperature, with tetrahydrofuran (thf), tetrahydropyran (thp), dioxane and tetrahydrothiophene (tht) afforded, respectively, [Mo(O)Cl-3(thf)](2), 1, and MoCl4(L)(2) (L = thp, 2; dioxane, 3; tht, 4), in 81-87% yields. The molecular structures of 1, 2 and 4 were ascertained by X-ray diffractometry. DFT and spectroscopic (IR, NMR) studies were carried out in order to shed light on thermodynamic and kinetic aspects of the reaction pathways.

The interaction of molybdenum pentachloride with O- and S-heterocycles / Lucilla Favero; Fabio Marchetti; Guido Pampaloni; Stefano Zacchini. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - 43:(2014), pp. 495-504. [10.1039/c3dt52271g]

The interaction of molybdenum pentachloride with O- and S-heterocycles

ZACCHINI, STEFANO
2014

Abstract

The 1 : 2 molar reactions of MoCl5, in dichloromethane at room temperature, with tetrahydrofuran (thf), tetrahydropyran (thp), dioxane and tetrahydrothiophene (tht) afforded, respectively, [Mo(O)Cl-3(thf)](2), 1, and MoCl4(L)(2) (L = thp, 2; dioxane, 3; tht, 4), in 81-87% yields. The molecular structures of 1, 2 and 4 were ascertained by X-ray diffractometry. DFT and spectroscopic (IR, NMR) studies were carried out in order to shed light on thermodynamic and kinetic aspects of the reaction pathways.
2014
The interaction of molybdenum pentachloride with O- and S-heterocycles / Lucilla Favero; Fabio Marchetti; Guido Pampaloni; Stefano Zacchini. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - STAMPA. - 43:(2014), pp. 495-504. [10.1039/c3dt52271g]
Lucilla Favero; Fabio Marchetti; Guido Pampaloni; Stefano Zacchini
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/303920
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