The preparation of a new thiophenic dimer partially derivatized with a bromohexylic chain is described. Its polymerization under mild oxidative conditions leads to a polythiophene with a degree of functionalization of 50% and higly soluble in organic solvents. The product has been fully characterized by FT-I, 1H and 13C NMR using one and two-dimensional techniques as well as by SEC and thermal analysis. Solvatochromic effects of the new polymer have been investigated in different mixtures, underlining its self-assembling capability even in solvated states.

Novel Thiophenic Copolymer as a Multi-Purpose Macromolecular Intermediate

PAGANIN, LUISA;COSTA BIZZARRI, PAOLO;LANZI, MASSIMILIANO;CESARI, GAIA;BERTINELLI, FRANCO;
2006

Abstract

The preparation of a new thiophenic dimer partially derivatized with a bromohexylic chain is described. Its polymerization under mild oxidative conditions leads to a polythiophene with a degree of functionalization of 50% and higly soluble in organic solvents. The product has been fully characterized by FT-I, 1H and 13C NMR using one and two-dimensional techniques as well as by SEC and thermal analysis. Solvatochromic effects of the new polymer have been investigated in different mixtures, underlining its self-assembling capability even in solvated states.
L. Paganin; P. Costa Bizzarri; M. Lanzi; G. Cesari; F. Bertinelli; R. Cagnoli; A. Mucci
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/27441
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