A novel method for the preparation of beta-fused porphyrin dyads was developed that exploits a one-pot reaction of 2,3-diaminoporphyrins with diethyl oxalate. This approach provides good yields of the zinc beta-fused dyad and the corresponding free-base, opening the way for preparation of several metal derivatives to permit modulation of optoelectronic characteristics for commercial applications. (C) 2013 Elsevier Ltd. All rights reserved.

Beta-Pyrazino-fused tetrarylporphyrins

PRODI, LUCA;GENOVESE, DAMIANO;
2013

Abstract

A novel method for the preparation of beta-fused porphyrin dyads was developed that exploits a one-pot reaction of 2,3-diaminoporphyrins with diethyl oxalate. This approach provides good yields of the zinc beta-fused dyad and the corresponding free-base, opening the way for preparation of several metal derivatives to permit modulation of optoelectronic characteristics for commercial applications. (C) 2013 Elsevier Ltd. All rights reserved.
Federica Mandoj;Sara Nardis;Rajesh Pudi;Larisa Lvova;Frank R. Fronczek;Kevin M. Smith;Luca Prodi;Damiano Genovese;Roberto Paolesse
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11585/267901
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