The rotational spectra of trifluoroanisole (trifluoromethoxybenzene, C6H5OCF3) and of its 13C and 18O isotopologues in natural abundance have been measured in a supersonic expansion with pulsed-jet Fourier transform microwave spectroscopy. The spectrum is consistent with a perpendicular conformation of the CF3 group with respect to the phenyl ring.
Lu Kang, Stewart E. Novick, Qian Gou, Lorenzo Spada, Montserrat Vallejo-López, Walther Caminati (2014). The shape of trifluoromethoxybenzene. JOURNAL OF MOLECULAR SPECTROSCOPY, 297, 32-34 [10.1016/j.jms.2014.01.011].
The shape of trifluoromethoxybenzene
GOU, QIAN;SPADA, LORENZO;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of trifluoroanisole (trifluoromethoxybenzene, C6H5OCF3) and of its 13C and 18O isotopologues in natural abundance have been measured in a supersonic expansion with pulsed-jet Fourier transform microwave spectroscopy. The spectrum is consistent with a perpendicular conformation of the CF3 group with respect to the phenyl ring.File in questo prodotto:
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