The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 group
Luca Evangelisti, Gang Feng, Qian Gou, Jens-Uwe Grabow, Walther Caminati (2014). Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl–Dimethyl Ether. JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY, 118, 579-582 [10.1021/jp411372m].
Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl–Dimethyl Ether
EVANGELISTI, LUCA;FENG, GANG;GOU, QIAN;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 groupFile in questo prodotto:
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