The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 group
Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl–Dimethyl Ether
EVANGELISTI, LUCA;FENG, GANG;GOU, QIAN;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 groupFile in questo prodotto:
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