The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 group
Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl–Dimethyl Ether / Luca Evangelisti;Gang Feng;Qian Gou;Jens-Uwe Grabow;Walther Caminati. - In: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY. - ISSN 1089-5639. - STAMPA. - 118:(2014), pp. 579-582. [10.1021/jp411372m]
Halogen Bond and Free Internal Rotation: The Microwave Spectrum of CF3Cl–Dimethyl Ether
EVANGELISTI, LUCA;FENG, GANG;GOU, QIAN;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of two isotopologues of the molecular complex CF3Cl−dimethyl ether have been measured with pulsed jet Fourier transform microwave spectroscopy. The rotational spectrum encodes information on the global minimum configuration, stabilized by a Cl···O halogen bond, and on the almost free rotation of the −CF3 groupI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
