The rotational spectra of four conformers of the acrylic acid—difluoroacetic acid adduct (CH2=CHCOOH– CHF2COOH, AA-DFA) are reported and information on their internal dynamics is supplied. This represents an unprecedented result for the conformational analysis, with microwave spectroscopy, of such a heavy molecular adduct
Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid-Difluoroacetic Acid Adduct / Gang Feng;Qian Gou;Luca Evangelisti;Walther Caminati. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 53:(2014), pp. 530-534. [10.1002/anie.201308459]
Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid-Difluoroacetic Acid Adduct
FENG, GANG;GOU, QIAN;EVANGELISTI, LUCA;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of four conformers of the acrylic acid—difluoroacetic acid adduct (CH2=CHCOOH– CHF2COOH, AA-DFA) are reported and information on their internal dynamics is supplied. This represents an unprecedented result for the conformational analysis, with microwave spectroscopy, of such a heavy molecular adductI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
