The rotational spectra of four conformers of the acrylic acid—difluoroacetic acid adduct (CH2=CHCOOH– CHF2COOH, AA-DFA) are reported and information on their internal dynamics is supplied. This represents an unprecedented result for the conformational analysis, with microwave spectroscopy, of such a heavy molecular adduct
Gang Feng, Qian Gou, Luca Evangelisti, Walther Caminati (2014). Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid-Difluoroacetic Acid Adduct. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 53, 530-534 [10.1002/anie.201308459].
Frontiers in Rotational Spectroscopy: Shapes and Tunneling Dynamics of the Four Conformers of the Acrylic Acid-Difluoroacetic Acid Adduct
FENG, GANG;GOU, QIAN;EVANGELISTI, LUCA;CAMINATI, WALTHER
2014
Abstract
The rotational spectra of four conformers of the acrylic acid—difluoroacetic acid adduct (CH2=CHCOOH– CHF2COOH, AA-DFA) are reported and information on their internal dynamics is supplied. This represents an unprecedented result for the conformational analysis, with microwave spectroscopy, of such a heavy molecular adductFile in questo prodotto:
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