Excess molar enthalpies, HEm, of binary liquid mixtures containing dibutyl ether or ethylene glycol monoethyl ether or ethylene glycol dimethyl ether or ethylene glycol diethyl ether or diethylene glycol ethyl ether or diethylene glycol diethyl ether or triethylene glycol monoethyl ether + benzyl alcohol have been measured over the entire range of composition at 308.15 K and at atmospheric pressure using a flow microcalorimeter. Data were fitted to the Redlich-Kister equation. The results show how the enthalpy of mixing is influenced by both the steric and electronic characteristic of the terminal groups that belonging the OP = [CH2OCH2] central unit of the ether, and on the hydrogen bonding.
C. Castellari (2006). Excess Molar Enthalpies and Hydrogen Bonding in Binary Mixtures Containing Ethers and Benzyl Alchohol at 308.15 K and Atmospheric Pressure. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 51, 599-603 [10.1021/je0504212].
Excess Molar Enthalpies and Hydrogen Bonding in Binary Mixtures Containing Ethers and Benzyl Alchohol at 308.15 K and Atmospheric Pressure.
CASTELLARI, CARLO
2006
Abstract
Excess molar enthalpies, HEm, of binary liquid mixtures containing dibutyl ether or ethylene glycol monoethyl ether or ethylene glycol dimethyl ether or ethylene glycol diethyl ether or diethylene glycol ethyl ether or diethylene glycol diethyl ether or triethylene glycol monoethyl ether + benzyl alcohol have been measured over the entire range of composition at 308.15 K and at atmospheric pressure using a flow microcalorimeter. Data were fitted to the Redlich-Kister equation. The results show how the enthalpy of mixing is influenced by both the steric and electronic characteristic of the terminal groups that belonging the OP = [CH2OCH2] central unit of the ether, and on the hydrogen bonding.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
