The radical reaction of tributyltin hydride with azidoalkylmalononitriles bearing variously substituted alkenyl groups gives rise to pyrrolopyrroles and pyrrolopyridines through tandem cyclization reaction of initial stannylaminyl radicals onto either nitrile group followed by cyclization of ensuing aminoiminyl radicals onto the alkenylic moiety
L. Benati, G. Bencivenni, R. Leardini, M. Minozzi, D. Nanni, R. Scialpi, et al. (2004). Cyclisations of N-Stannylaminyl Radicals onto Nitriles: a new entry to pyrrolipyrroles and pyrrolopyridines. URBINO : s.n.
Cyclisations of N-Stannylaminyl Radicals onto Nitriles: a new entry to pyrrolipyrroles and pyrrolopyridines
BENATI, MARIA LUISA;BENCIVENNI, GIORGIO;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;ZANARDI, GIUSEPPE
2004
Abstract
The radical reaction of tributyltin hydride with azidoalkylmalononitriles bearing variously substituted alkenyl groups gives rise to pyrrolopyrroles and pyrrolopyridines through tandem cyclization reaction of initial stannylaminyl radicals onto either nitrile group followed by cyclization of ensuing aminoiminyl radicals onto the alkenylic moietyFile in questo prodotto:
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