Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.

A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State

MOLLOY, JENNIFER;MATTA, MICAELA;BERGAMINI, GIACOMO;ZERBETTO, FRANCESCO;CERONI, PAOLA;
2013

Abstract

Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.
Kalman Toth;Jennifer K. Molloy;Micaela Matta;Benoît Heinrich;Daniel Guillon;Giacomo Bergamini;Francesco Zerbetto;Bertrand Donnio;Paola Ceroni;Delphine Felder-Flesch
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11585/191560
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