Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.
Kalman Toth, Jennifer K. Molloy, Micaela Matta, Benoît Heinrich, Daniel Guillon, Giacomo Bergamini, et al. (2013). A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 52, 12303-12307 [10.1002/anie.201305536].
A Strongly Emitting Liquid-Crystalline Derivative of Y3N@C80: Bright and Long-Lived Near-IR Luminescence from a Charge Transfer State
MOLLOY, JENNIFER;MATTA, MICAELA;BERGAMINI, GIACOMO;ZERBETTO, FRANCESCO;CERONI, PAOLA;
2013
Abstract
Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core-shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
