The Ni6C(CO)9(AuPPh3)4 bimetallic carbide carbonyl cluster was obtained from the reaction of [Ni9C(CO)17]2– with Au(PPh3)Cl. It contains a rare carbon-centered (distorted) Ni6C octahedral core decorated by four Au(PPh3) fragments. These are μ3-bonded to four contiguous Ni3-triangular faces and display weak intramolecular Au···Au d10–d10 interactions. The cluster has been characterized in the solid state on two different solvato crystals, i.e., Ni6C(CO)9(AuPPh3)4·THF and Ni6C(CO)9(AuPPh3)4·THF·0.5C6H14. The two solvates show some interesting differences concerning the weak Au···Au contacts. Density functional theory calculations have demonstrated that the presence of the two isomers is related to solid-state packing effects and not to the existence of two double minima in the potential energy surface. This, in turn, confirms that Au···Au d10–d10 interactions are rather soft and thus influenced also by weak van der Waals forces because of the interaction of the cluster with the cocrystallized solvent molecules.
Iacopo Ciabatti, Cristina Femoni, Maria Carmela Iapalucci, Andrea Ienco, Giuliano Longoni, Gabriele Manca, et al. (2013). Intramolecular d10–d10 Interactions in a Ni6C(CO)9(AuPPh3)4 Bimetallic Nickel–Gold Carbide Carbonyl Cluster. INORGANIC CHEMISTRY, 52, 10559-10565 [10.1021/ic401540s].
Intramolecular d10–d10 Interactions in a Ni6C(CO)9(AuPPh3)4 Bimetallic Nickel–Gold Carbide Carbonyl Cluster
CIABATTI, IACOPO;FEMONI, CRISTINA;IAPALUCCI, MARIA CARMELA;LONGONI, GIULIANO;ZACCHINI, STEFANO
2013
Abstract
The Ni6C(CO)9(AuPPh3)4 bimetallic carbide carbonyl cluster was obtained from the reaction of [Ni9C(CO)17]2– with Au(PPh3)Cl. It contains a rare carbon-centered (distorted) Ni6C octahedral core decorated by four Au(PPh3) fragments. These are μ3-bonded to four contiguous Ni3-triangular faces and display weak intramolecular Au···Au d10–d10 interactions. The cluster has been characterized in the solid state on two different solvato crystals, i.e., Ni6C(CO)9(AuPPh3)4·THF and Ni6C(CO)9(AuPPh3)4·THF·0.5C6H14. The two solvates show some interesting differences concerning the weak Au···Au contacts. Density functional theory calculations have demonstrated that the presence of the two isomers is related to solid-state packing effects and not to the existence of two double minima in the potential energy surface. This, in turn, confirms that Au···Au d10–d10 interactions are rather soft and thus influenced also by weak van der Waals forces because of the interaction of the cluster with the cocrystallized solvent molecules.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
