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EnglishWith the aim of designing a new calcium receptor, the synthesis and the conformational analysis of a small library of dipeptides having general formula Ac-Oxx-L-Xaa-OBn [Oxx = L-Oxd, (4S,5R)-4-methyl-5-carboxyoxazolidin-2-one; D-Oxd, (4R,5S)-4-methyl-5-carboxyoxazolidin-2-one; or D-Oxac (4R)-(2-oxo-1,3-oxazolidin-4-yl)-acetic acid] is reported. Ac-L-Oxd-L-Ala-OBn was identified as the most promising compound by MS-ESI analysis and this outcome was confirmed by photoluminescence spectroscopy.
| Titolo: | Development of New Calcium Receptors Based on Oxazolidin-2-ones Containing Pseudopeptides | |
| Autore/i: | LUPPI, GIANLUIGI; GARELLI, ANDREA; PRODI, LUCA; Q. B. Broxterman; B. Kaptein; TOMASINI, CLAUDIA | |
| Autore/i Unibo: | ||
| Anno: | 2005 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/b501017a | |
| Abstract: | With the aim of designing a new calcium receptor, the synthesis and the conformational analysis of a small library of dipeptides having general formula Ac-Oxx-L-Xaa-OBn [Oxx = L-Oxd, (4S,5R)-4-methyl-5-carboxyoxazolidin-2-one; D-Oxd, (4R,5S)-4-methyl-5-carboxyoxazolidin-2-one; or D-Oxac (4R)-(2-oxo-1,3-oxazolidin-4-yl)-acetic acid] is reported. Ac-L-Oxd-L-Ala-OBn was identified as the most promising compound by MS-ESI analysis and this outcome was confirmed by photoluminescence spectroscopy. | |
| Data prodotto definitivo in UGOV: | 2005-10-17 11:12:58 | |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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