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EnglishA review. After more than 125 yr, the Friedel-Crafts alkylation is still one of the most studied and most utilized reactions in org. synthesis. What is the secret of this astonishing success Perhaps the great versatility in; scope and applicability continues to justify its crucial role in the synthesis of more and more complex mols. However, it has taken more than a century for asym. catalytic versions of this reaction to be developed and subsequently extended to a range of arom. compds. and alkylating agents. Herein recent developments in the design and use of catalytic and stereoselective strategies for the alkylation of arom. systems and synthesis of a wide range of polyfunctionalized enantiomerically enriched compds. were reviewed.
| Titolo: | New Catalytic Approaches in the Enantioselective Friedel-Crafts Alkylation Reaction |
| Autore/i: | BANDINI, MARCO; MELLONI, ALFONSO; UMANI RONCHI, ACHILLE |
| Autore/i Unibo: | |
| Anno: | 2004 |
| Rivista: | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.200301679 |
| Abstract: | A review. After more than 125 yr, the Friedel-Crafts alkylation is still one of the most studied and most utilized reactions in org. synthesis. What is the secret of this astonishing success Perhaps the great versatility in; scope and applicability continues to justify its crucial role in the synthesis of more and more complex mols. However, it has taken more than a century for asym. catalytic versions of this reaction to be developed and subsequently extended to a range of arom. compds. and alkylating agents. Herein recent developments in the design and use of catalytic and stereoselective strategies for the alkylation of arom. systems and synthesis of a wide range of polyfunctionalized enantiomerically enriched compds. were reviewed. |
| Data prodotto definitivo in UGOV: | 2005-10-18 14:14:21 |
| Appare nelle tipologie: | 1.01 Articolo in rivista |
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http://hdl.handle.net/11585/1854
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