Novel tri- and pentablock unsymmetrical semifluorinated unbranched ethers of general formula RfCH2O(CH2)3R0 f, containing perfluorinated chains with C 6, have been synthesized and characterized. The synthesis was performed in two steps: perfluoroalkyl iodide addition to fluoroalkyl allyl ethers followed by reduction of the C–I bond via heterogeneous catalytic hydrogenation with palladium on carbon.
Dario Lazzari, Maria Cristina Cassani, Gavino Solinas, Marisa Pretto (2013). Fluoroalkyl allyl ethers: Useful building blocks for the synthesis of environmentally safer fluorinated multiblock molecules. JOURNAL OF FLUORINE CHEMISTRY, 156, 34-37 [10.1016/j.jfluchem.2013.08.003].
Fluoroalkyl allyl ethers: Useful building blocks for the synthesis of environmentally safer fluorinated multiblock molecules
CASSANI, MARIA CRISTINA;SOLINAS, GAVINO;
2013
Abstract
Novel tri- and pentablock unsymmetrical semifluorinated unbranched ethers of general formula RfCH2O(CH2)3R0 f, containing perfluorinated chains with C 6, have been synthesized and characterized. The synthesis was performed in two steps: perfluoroalkyl iodide addition to fluoroalkyl allyl ethers followed by reduction of the C–I bond via heterogeneous catalytic hydrogenation with palladium on carbon.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
