The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]-arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.
Phillip J. Wright, Sara Muzzioli, Brian W. Skelton, Paolo Raiteri, Jackson Lee, George Koutsantonis, et al. (2013). One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation. DALTON TRANSACTIONS, 42, 8188-8191 [10.1039/c3dt50988e].
One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation
MUZZIOLI, SARA;STAGNI, STEFANO;
2013
Abstract
The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]-arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.File in questo prodotto:
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