The pure rotational spectrum of 13C2HD was recorded in the range 100-700 GHz. Lines belonging to the ground vibrational state were observed from J″ = 1 to J″ = 11. Several absorption lines were also detected in the bending states v4 = 1 (Π), v5 = 1 (Π), v4 = 2 (Σ+ and Δ), v5 = 2 (Σ+ and Δ), v4 = v5 = 1 (Σ-, Σ+ and Δ), v4 = 3 (Π and Φ) and v5 = 3 (Π and Φ). The transition frequencies measured in this work were fitted together with all the infrared lines available in the literature. The global fit allowed a very accurate determination of the vibrational, rotational and ℓ-type interaction parameters for the bending states of this molecule. © 2012 Copyright Taylor and Francis Group, LLC.
The rotational spectrum of 13C2HD in the ground and excited bending states / C. D. Esposti; L. Dore; L. Fusina; F. Tamassia. - In: MOLECULAR PHYSICS. - ISSN 0026-8976. - STAMPA. - 111:7(2013), pp. 896-902. [10.1080/00268976.2012.756127]
The rotational spectrum of 13C2HD in the ground and excited bending states
DEGLI ESPOSTI, CLAUDIO;DORE, LUCA;FUSINA, LUCIANO;TAMASSIA, FILIPPO
2013
Abstract
The pure rotational spectrum of 13C2HD was recorded in the range 100-700 GHz. Lines belonging to the ground vibrational state were observed from J″ = 1 to J″ = 11. Several absorption lines were also detected in the bending states v4 = 1 (Π), v5 = 1 (Π), v4 = 2 (Σ+ and Δ), v5 = 2 (Σ+ and Δ), v4 = v5 = 1 (Σ-, Σ+ and Δ), v4 = 3 (Π and Φ) and v5 = 3 (Π and Φ). The transition frequencies measured in this work were fitted together with all the infrared lines available in the literature. The global fit allowed a very accurate determination of the vibrational, rotational and ℓ-type interaction parameters for the bending states of this molecule. © 2012 Copyright Taylor and Francis Group, LLC.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
