The pure rotational spectrum of 13C2HD was recorded in the range 100-700 GHz. Lines belonging to the ground vibrational state were observed from J″ = 1 to J″ = 11. Several absorption lines were also detected in the bending states v4 = 1 (Π), v5 = 1 (Π), v4 = 2 (Σ+ and Δ), v5 = 2 (Σ+ and Δ), v4 = v5 = 1 (Σ-, Σ+ and Δ), v4 = 3 (Π and Φ) and v5 = 3 (Π and Φ). The transition frequencies measured in this work were fitted together with all the infrared lines available in the literature. The global fit allowed a very accurate determination of the vibrational, rotational and ℓ-type interaction parameters for the bending states of this molecule. © 2012 Copyright Taylor and Francis Group, LLC.
C. D. Esposti, L. Dore, L. Fusina, F. Tamassia (2013). The rotational spectrum of 13C2HD in the ground and excited bending states. MOLECULAR PHYSICS, 111(7), 896-902 [10.1080/00268976.2012.756127].
The rotational spectrum of 13C2HD in the ground and excited bending states
DEGLI ESPOSTI, CLAUDIO;DORE, LUCA;FUSINA, LUCIANO;TAMASSIA, FILIPPO
2013
Abstract
The pure rotational spectrum of 13C2HD was recorded in the range 100-700 GHz. Lines belonging to the ground vibrational state were observed from J″ = 1 to J″ = 11. Several absorption lines were also detected in the bending states v4 = 1 (Π), v5 = 1 (Π), v4 = 2 (Σ+ and Δ), v5 = 2 (Σ+ and Δ), v4 = v5 = 1 (Σ-, Σ+ and Δ), v4 = 3 (Π and Φ) and v5 = 3 (Π and Φ). The transition frequencies measured in this work were fitted together with all the infrared lines available in the literature. The global fit allowed a very accurate determination of the vibrational, rotational and ℓ-type interaction parameters for the bending states of this molecule. © 2012 Copyright Taylor and Francis Group, LLC.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
