Diastereoselective SN1-type reactions have been known for many years and have been used in the synthesis of many natural products. It has recently been shown that chiral nucleophiles, obtained using organocatalytic methodologies, can react with highly reactive carbenium ions in a stereoselective fashion. Based on this, carbenium ions can be applied in asymmetric catalytic reactions.
A. Gualandi, P. G. Cozzi (2013). Stereoselective Organocatalytic Alkylations with Carbenium Ions. SYNLETT, 24, 281-296 [10.1055/s-0032-1317939].
Stereoselective Organocatalytic Alkylations with Carbenium Ions
GUALANDI, ANDREA;COZZI, PIER GIORGIO
2013
Abstract
Diastereoselective SN1-type reactions have been known for many years and have been used in the synthesis of many natural products. It has recently been shown that chiral nucleophiles, obtained using organocatalytic methodologies, can react with highly reactive carbenium ions in a stereoselective fashion. Based on this, carbenium ions can be applied in asymmetric catalytic reactions.File in questo prodotto:
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