Magnesium nanoparticles coated by a native oxide shell and decorated by palladium clusters were synthesized by the inert gas condensation technique. The kinetics and thermodynamics of hydrogen sorption were investigated by Sieverts measurements at high temperature and by optical hydrogenography close to ambient temperature. The structure and morphology of the nanoparticles were studied by electron microscopy and X-ray diffraction both in the as-prepared state and after hydrogen sorption cycles.
L. Pasquini, M. Brighi, A. Montone, M. Vittori Antisari, B. Dam, V. Palmisano, et al. (2012). Magnesium Nanoparticles for Hydrogen Storage: Structure, Kinetics and Thermodynamics. BRISTOL : Institute of Physics [10.1088/1757-899X/38/1/012001].
Magnesium Nanoparticles for Hydrogen Storage: Structure, Kinetics and Thermodynamics
PASQUINI, LUCA;BRIGHI, MATTEO;BONETTI, ENNIO
2012
Abstract
Magnesium nanoparticles coated by a native oxide shell and decorated by palladium clusters were synthesized by the inert gas condensation technique. The kinetics and thermodynamics of hydrogen sorption were investigated by Sieverts measurements at high temperature and by optical hydrogenography close to ambient temperature. The structure and morphology of the nanoparticles were studied by electron microscopy and X-ray diffraction both in the as-prepared state and after hydrogen sorption cycles.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
