We have studied the pressure-induced neutral-ionic phase transition of tetrathiafulvalene-chloranil (TTF-CA) with polarized infrared absorption spectra of single crystals inside a diamond anvil cell (DAC). The evolution of the phase transition is complex, implying at least two steps. The nature of the intermediate regime is briefly discussed.
High-pressure optical study of the neutral-ionic phase transition in TTF-CA / M. Masino; A. Girlando; A. Brillante; R.G. Della Valle; E. Venuti. - In: MATERIALS SCIENCE. - ISSN 0137-1339. - STAMPA. - 22:4(2004), pp. 333-337.
High-pressure optical study of the neutral-ionic phase transition in TTF-CA
BRILLANTE, ALDO;DELLA VALLE, RAFFAELE GUIDO;VENUTI, ELISABETTA
2004
Abstract
We have studied the pressure-induced neutral-ionic phase transition of tetrathiafulvalene-chloranil (TTF-CA) with polarized infrared absorption spectra of single crystals inside a diamond anvil cell (DAC). The evolution of the phase transition is complex, implying at least two steps. The nature of the intermediate regime is briefly discussed.File in questo prodotto:
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