A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.
L. Bernardi, E. Indrigo, S. Pollicino, A. Ricci (2012). Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines. CHEMICAL COMMUNICATIONS, 48, 1428-1430 [10.1039/c0cc05777k].
Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines
BERNARDI, LUCA;RICCI, ALFREDO MARCO
2012
Abstract
A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.File in questo prodotto:
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