One-way path: A non-symmetric molecular axle threads a crown ether ring and is subsequently expelled along the same threading direction upon application of photochemical and chemical stimuli. The system relies on tailor-made control of the thermodynamic and kinetic properties of the system according to a flashing ratchet mechanism.
M. Baroncini, S. Silvi, M. Venturi, A. Credi (2012). Photoactivated directionally controlled transit of a non-symmetric molecular axle through a macrocycle. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 51, 4223-4226 [10.1002/anie.201200555].
Photoactivated directionally controlled transit of a non-symmetric molecular axle through a macrocycle
BARONCINI, MASSIMO;SILVI, SERENA;VENTURI, MARGHERITA;CREDI, ALBERTO
2012
Abstract
One-way path: A non-symmetric molecular axle threads a crown ether ring and is subsequently expelled along the same threading direction upon application of photochemical and chemical stimuli. The system relies on tailor-made control of the thermodynamic and kinetic properties of the system according to a flashing ratchet mechanism.File in questo prodotto:
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