(+)-syn-Benzotriborneol forms stable complexes with one molecule of water. This is due to the ability of the host to form three hydrogen bonds with water, to act simultaneously as a hydrogen-bond acceptor and donor, and to a perfect geometrical match between the pair. We report experimental (X-ray and neutron diffraction, VT NMR, DSC, TGA) and stereochemical studies carried out to elucidate and quantify the molecular and thermodynamic aspects of this supramolecular complex
(+)-syn-Benzotriborneol: an enantiopure C3-symmetric receptor for water / F. Fabris; O. De Lucchi; I. Nardini; M. Crisma; A. Mazzanti; S. A. Mason; M-H. Lemée-Cailleau; F. A. Scaramuzzo; C. Zonta.. - In: ORGANIC & BIOMOLECULAR CHEMISTRY. - ISSN 1477-0520. - STAMPA. - 10:(2012), pp. 2464-2469. [10.1039/c2ob06774a]
(+)-syn-Benzotriborneol: an enantiopure C3-symmetric receptor for water.
MAZZANTI, ANDREA;
2012
Abstract
(+)-syn-Benzotriborneol forms stable complexes with one molecule of water. This is due to the ability of the host to form three hydrogen bonds with water, to act simultaneously as a hydrogen-bond acceptor and donor, and to a perfect geometrical match between the pair. We report experimental (X-ray and neutron diffraction, VT NMR, DSC, TGA) and stereochemical studies carried out to elucidate and quantify the molecular and thermodynamic aspects of this supramolecular complexI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
